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Chlorine dioxide is a chemical compound with the formula ClO2 that exists as yellowish-green gas above 11 °C, a reddish-brown liquid between 11 °C and −59 °C, and as bright orange crystals below −59 °C. It is an oxidizing agent, able to transfer oxygen to a variety of substrates, while gaining one or more electrons via oxidation-reduction (redox). It does not hydrolyze when it enters water, and is usually handled as a dissolved gas in solution in water. Potential hazards with chlorine dioxide include health concerns, explosiveness and fire ignition. It is commonly used as a bleach.

Chlorine dioxide was discovered in 1811 by Sir Humphry Davy and has been widely used for bleaching purposes in the paper industry, and for treatment of drinking water.More recent developments have extended its application into food processing, disinfection of premises and vehicles, mold eradication, air disinfection and odor control, treatment of swimming pools, dental applications, and wound cleansing.

The compound has been fraudulently marketed as an ingestible cure for a wide range of diseases, including childhood autism and COVID-19. Children who have been given enemas of chlorine dioxide as a supposed cure for childhood autism have suffered life-threatening ailments. The U.S. Food and Drug Administration (FDA) has stated that ingestion or other internal use of chlorine dioxide (other than perhaps oral rinsing under dentist supervision) has no health benefits and it should not be used internally for any reason.