Phenols and alcohols have both the same functional group `(-OH)` but phenols are stronger acids than alcohols. This is mainly due to the reason that the phenoxide ion `(C_(6)H_(5)O^(Ɵ))` left after the release of `H^(+)` ion in phenol is resonance stabilised while the alkoxide ion `(RO^(Ɵ))` in alcohols does not show similar characteristics. The electron withdrawing groups tend to increase the acidic strengths of phenols while electron releasing groups tend to decrease it. the effect of both types of groups is more pronounced when present at the para position than when these are present at the ortho position in the ring. However, their effect at the meta position is relatively very small.
The increasing order of reactivity of `1^(@), 2^(@)` and `3^(@)` alcohols towards sodium metal is
A. `1^(@) lt 2^(@) lt 3^(@)`
B. `1^(@) lt 3^(@) lt 2^(@)`
C. `3^(@) lt 2^(@) lt 1^(@)`
D. `2^(@) lt 1^(@) lt 3^(@)`

General Awareness ALCOHOLS-AND-PHENOLS IN GENERAL AWARENESS 2 years ago

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Correct Answer - C
It involves the cleavage of `O-H` bond which is easiest in `1^(@)` alcohols and most difficult in `3^(@)` alcohols.

Posted on 06 Oct 2022, this text provides information on General Awareness related to ALCOHOLS-AND-PHENOLS IN GENERAL AWARENESS. Please note that while accuracy is prioritized, the data presented might not be entirely correct or up-to-date. This information is offered for general knowledge and informational purposes only, and should not be considered as a substitute for professional advice.

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