C{{H}_{2}}+HBr\xrightarrow{\text{peroxide}}\] \[\underset{n-\text{propyl}\,\text{bromide}}{\mathop{C{{H}_{3}}-C{{H}_{2}}-C{{H}_{2}}-B}}\,r\] In presence of peroxide ADDITION takes place according to Anti Markownikoff?s RULE and hydrogen atom goes to that CARBON atom which is less hydrogenated.

"> C{{H}_{2}}+HBr\xrightarrow{\text{peroxide}}\] \[\underset{n-\text{propyl}\,\text{bromide}}{\mathop{C{{H}_{3}}-C{{H}_{2}}-C{{H}_{2}}-B}}\,r\] In presence of peroxide ADDITION takes place according to Anti Markownikoff?s RULE and hydrogen atom goes to that CARBON atom which is less hydrogenated.

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sThe major product formed when propene reacts with HBr in presence of peroxides is [NCERT 1980; CBSE PMT 1989]

Joint Entrance Exam - Main (JEE Main) Chemistry in Joint Entrance Exam - Main (JEE Main) 1 year ago

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\[CH-CH=C{{H}_{2}}+HBr\xrightarrow{\text{peroxide}}\] \[\underset{n-\text{propyl}\,\text{bromide}}{\mathop{C{{H}_{3}}-C{{H}_{2}}-C{{H}_{2}}-B}}\,r\] In presence of peroxide ADDITION takes place according to Anti Markownikoff?s RULE and hydrogen atom goes to that CARBON atom which is less hydrogenated.

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