POTENTIAL at centre is ZERO, then \[{{V}_{1}}+{{V}_{2}}+{{V}_{3}}+{{V}_{4}}=0\] \[-\frac{kQ}{r}-\frac{kq}{r}+\frac{k2Q}{r}+\frac{k2q}{r}=0\] \[-Q-q+2q+2Q=0\] \[Q=-q\]